Observation of Structural Phase Changes Driven by Electrostatic Gating

We predicted that 2H-to-1T’ structural phase transformations in monolayer MoTe2 can be driven by electrostatic gating. Our predictions were confirmed in the lab, where our collaborators employed ionic liquids to gate the monolayer (a). Raman spectroscopy (b) and second harmonic generation studies confirm the phase transition takes place when increasing the gate voltage.

We predict that this mechanism could consume much less energy than existing thermally-driven phase-change memory devices made of Ge2Sb2Te(c).  We compare the energy consumption to the electrostatic gating case of monolayer MoTe2 (d), which uses voltage and charge to induce the transformation.

We find that the theoretical minimum energy required to change phase in monolayer MoTe2 is 100-10,000 times lower than the energy required with state of the art Ge2Sb2Te5 phase change devices (e).

Designing Materials to Revolutionize and Engineer our Future (DMREF)