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Hybrid Metamaterials with Integrated Magnetic and Plasmonic Non-Noble Metal Nanostructures

Sep 16, 2025

A numerical framework was developed to simulate the processing of  multicomponent metallic pillars embedded in a BaTiO₃ matrix. The model combines the kinetics of solute diffusion and mechanical equilibrium. Numerical results help explain the experimental morphology in a Co-Cu pillar. Specifically:

  • The simulation results show great agreement with the experimental observations of the copper-cobalt pillar morphology.

  • Cu outer shell is a result of the interplay between mechanical and chemical free energy in the pillar.

  • Morphology that minimizes the overall internal stresses of the pillar is favored.

  • For square morphologies, a “candy”-like morphology is favored as it minimizes the mechanical energy of the pillar plus matrix system.

  • For circular morphologies, a core-shell morphology is favored as the average amount of Cu in the pillar increases.

Authors

Edwin Garcia and Haiyan Wang (Purdue University)

Additional Materials

U.S. National Science Foundation and NSF DMREF, Materials for Our Future

This material is based upon work supported by the U.S. National Science Foundation Award No. 2015237. Any opinions, findings, and conclusions or recommendations expressed in this material are those of the author(s) and do not necessarily reflect the views of the U.S. National Science Foundation. This site is maintained collaboratively by principal investigators with NSF DMREF awards, independent of the NSF.