Acoustically Transformative Materials

Project Personnel

Sergei Sheiko

Principal Investigator

University of North Carolina at Chapel Hill

Krzysztof Matyjaszewski

Carnegie Mellon University

Michael Rubinstein

University of North Carolina at Chapel Hill

Funding Divisions

Division of Materials Research (DMR)

Many studies have focused on developing materials for conventional acoustic applications, such as ultrasound imaging, sound insulation, and geological logging. However, the design of materials that actively respond to sound and concurrently shift their acoustic and optical characteristics remains in its infancy. The goal of this project is to design acoustically responsive materials that alter their chemical structure, physical properties, and object shapes whenever they interact with sound waves enabling active modulation of acoustic properties including speed of sound, attenuation, and phononic band gaps. If compared to electromagnetic radiation, sound waves possess unique physical characteristics as they readily propagate through optically non-transparent materials, including liquids, solids, and gels (e.g., human body), where direct application of conventional stimuli, such as light and electric fields, is either physically or physiologically prohibited. This enables non-invasive interrogation of a wide range of materials properties and remote activation of various mechanochemical processes. Moreover, similar to electromagnetic radiation, sound can be focused both in space and in time. This opens intriguing opportunities to perform local modifications in a time-controlled, sequential manner. These materials may be utilized both in materials engineering for acoustic lithography and self-healing and in biomedical applications including non-invasive surgery, diagnostics, and drug-delivery.

Publications

Tissue‐Adaptive Materials with Independently Regulated Modulus and Transition Temperature
D. Zhang, E. Dashtimoghadam, F. Fahimipour, X. Hu, Q. Li, E. A. Bersenev, D. A. Ivanov, M. Vatankhah‐Varnoosfaderani, and S. S. Sheiko
11/11/2020
Nonlinear Elasticity and Swelling of Comb and Bottlebrush Networks
M. Jacobs, H. Liang, E. Dashtimoghadam, B. J. Morgan, S. S. Sheiko, and A. V. Dobrynin
6/28/2019
Comb and Bottlebrush Graft Copolymers in a Melt
H. Liang, Z. Wang, S. S. Sheiko, and A. V. Dobrynin
5/16/2019
Strained Bottlebrushes in Super-Soft Physical Networks
C. Clair, A. Lallam, M. Rosenthal, M. Sztucki, M. Vatankhah-Varnosfaderani, A. N. Keith, Y. Cong, H. Liang, A. V. Dobrynin, S. S. Sheiko, and D. A. Ivanov
4/23/2019
Transformation of gels via catalyst-free selective RAFT photoactivation
S. Shanmugam, J. Cuthbert, J. Flum, M. Fantin, C. Boyer, T. Kowalewski, and K. Matyjaszewski
1/1/2019
Universality of the Entanglement Plateau Modulus of Comb and Bottlebrush Polymer Melts
H. Liang, B. J. Morgan, G. Xie, M. R. Martinez, E. B. Zhulina, K. Matyjaszewski, S. S. Sheiko, and A. V. Dobrynin
12/3/2018
Molecular Bottlebrushes as Novel Materials
G. Xie, M. R. Martinez, M. Olszewski, S. S. Sheiko, and K. Matyjaszewski
10/8/2018
Benefits of Catalyzed Radical Termination: High-Yield Synthesis of Polyacrylate Molecular Bottlebrushes without Gelation
G. Xie, M. R. Martinez, W. F. M. Daniel, A. N. Keith, T. G. Ribelli, M. Fantin, S. S. Sheiko, and K. Matyjaszewski
8/7/2018
Encoding tissue mechanics in silicone
S. S. Sheiko, M. H. Everhart, A. V. Dobrynin, and M. Vatankhah-Varnosfaderani
5/30/2018
How To Measure Work of Adhesion and Surface Tension of Soft Polymeric Materials
Y. Tian, M. Ina, Z. Cao, S. S. Sheiko, and A. V. Dobrynin
5/18/2018
Chameleon-like elastomers with molecularly encoded strain-adaptive stiffening and coloration
M. Vatankhah-Varnosfaderani, A. N. Keith, Y. Cong, H. Liang, M. Rosenthal, M. Sztucki, C. Clair, S. Magonov, D. A. Ivanov, A. V. Dobrynin, and S. S. Sheiko
3/30/2018
Nanorheology of Entangled Polymer Melts
T. Ge, G. S. Grest, and M. Rubinstein
2/1/2018
Supersoft and Hyperelastic Polymer Networks with Brushlike Strands
H. Liang, S. S. Sheiko, and A. V. Dobrynin
1/11/2018
Exchange equilibria of carboxylate-terminated ligands at PbS nanocrystal surfaces
M. L. Kessler, H. E. Starr, R. R. Knauf, K. J. Rountree, and J. L. Dempsey
1/1/2018
Unraveling the Correlations between Conformation, Lubrication, and Chemical Stability of Bottlebrush Polymers at Interfaces
J. Faivre, B. R. Shrestha, G. Xie, T. Delair, L. David, K. Matyjaszewski, and X. Banquy
10/25/2017
Polymers at Liquid/Vapor Interface
B. L. Peters, D. Q. Pike, M. Rubinstein, and G. S. Grest
10/11/2017
Enhanced nanochannel translocation and localization of genomic DNA molecules using three-dimensional nanofunnels
J. Zhou, Y. Wang, L. D. Menard, S. Panyukov, M. Rubinstein, and J. M. Ramsey
10/9/2017
A Rheological Study of the Association and Dynamics of MUC5AC Gels
C. E. Wagner, B. S. Turner, M. Rubinstein, G. H. McKinley, and K. Ribbeck
10/2/2017
Mimicking biological stress–strain behaviour with synthetic elastomers
M. Vatankhah-Varnosfaderani, W. F. M. Daniel, M. H. Everhart, A. A. Pandya, H. Liang, K. Matyjaszewski, A. V. Dobrynin, and S. S. Sheiko
9/1/2017
Mesoporous nitrogen-doped carbons from PAN-based molecular bottlebrushes
R. Yuan, M. Kopeć, G. Xie, E. Gottlieb, J. W. Mohin, Z. Wang, M. Lamson, T. Kowalewski, and K. Matyjaszewski
9/1/2017
From Adhesion to Wetting: Contact Mechanics at the Surfaces of Super-Soft Brush-Like Elastomers
M. Ina, Z. Cao, M. Vatankhah-Varnoosfaderani, M. H. Everhart, W. F. M. Daniel, A. V. Dobrynin, and S. S. Sheiko
7/25/2017
Single-stranded nucleic acid elasticity arises from internal electrostatic tension
D. R. Jacobson, D. B. McIntosh, M. J. Stevens, M. Rubinstein, and O. A. Saleh
5/1/2017
Combs and Bottlebrushes in a Melt
H. Liang, Z. Cao, Z. Wang, S. S. Sheiko, and A. V. Dobrynin
4/11/2017
Heterografted Molecular Brushes as Stabilizers for Water-in-Oil Emulsions
G. Xie, P. Krys, R. D. Tilton, and K. Matyjaszewski
3/27/2017
Nanoparticle Motion in Entangled Melts of Linear and Nonconcatenated Ring Polymers
T. Ge, J. T. Kalathi, J. D. Halverson, G. S. Grest, and M. Rubinstein
2/13/2017
Programming molecular self-assembly of intrinsically disordered proteins containing sequences of low complexity
J. R. Simon, N. J. Carroll, M. Rubinstein, A. Chilkoti, and G. P. López
1/30/2017
Wear Protection without Surface Modification Using a Synergistic Mixture of Molecular Brushes and Linear Polymers
J. Faivre, B. R. Shrestha, J. Burdynska, G. Xie, F. Moldovan, T. Delair, S. Benayoun, L. David, K. Matyjaszewski, and X. Banquy
1/18/2017
Dynamics of Dual Networks: Strain Rate and Temperature Effects in Hydrogels with Reversible H-Bonds
X. Hu, J. Zhou, W. F. M. Daniel, M. Vatankhah-Varnoosfaderani, A. V. Dobrynin, and S. S. Sheiko
1/11/2017
Flory theory of randomly branched polymers
R. Everaers, A. Y. Grosberg, M. Rubinstein, and A. Rosa
1/1/2017
Preparation of ZnO hybrid nanoparticles by ATRP
H. Ding, J. Yan, Z. Wang, G. Xie, C. Mahoney, R. Ferebee, M. Zhong, W. F. M. Daniel, J. Pietrasik, S. S. Sheiko, C. J. Bettinger, M. R. Bockstaller, and K. Matyjaszewski
12/1/2016
Bottlebrush Elastomers: A New Platform for Freestanding Electroactuation
M. Vatankhah‐Varnoosfaderani, W. F. M. Daniel, A. P. Zhushma, Q. Li, B. J. Morgan, K. Matyjaszewski, D. P. Armstrong, R. J. Spontak, A. V. Dobrynin, and S. S. Sheiko
11/8/2016
Molecular structure of bottlebrush polymers in melts
J. Paturej, S. S. Sheiko, S. Panyukov, and M. Rubinstein
11/4/2016
Dynamics of Bottlebrush Networks
Z. Cao, W. F. M. Daniel, M. Vatankhah-Varnosfaderani, S. S. Sheiko, and A. V. Dobrynin
10/4/2016
Programming temporal shapeshifting
X. Hu, J. Zhou, M. Vatankhah-Varnosfaderani, W. F. M. Daniel, Q. Li, A. P. Zhushma, A. V. Dobrynin, and S. S. Sheiko
9/27/2016
Well-Defined Zwitterionic Microgels: Synthesis and Application as Acid-Resistant Microreactors
M. Vatankhah-Varnoosfaderani, M. Ina, H. Adelnia, Q. Li, A. P. Zhushma, L. J. Hall, and S. S. Sheiko
9/20/2016
Surface patterning of nanoparticles with polymer patches
R. M. Choueiri, E. Galati, H. Thérien-Aubin, A. Klinkova, E. M. Larin, A. Querejeta-Fernández, L. Han, H. L. Xin, O. Gang, E. B. Zhulina, M. Rubinstein, and E. Kumacheva
8/24/2016
Preparation of titania nanoparticles with tunable anisotropy and branched structures from core–shell molecular bottlebrushes
G. Xie, H. Ding, W. F. M. Daniel, Z. Wang, J. Pietrasik, S. S. Sheiko, and K. Matyjaszewski
8/1/2016
Surface-Anchored Poly(N-isopropylacrylamide) Orthogonal Gradient Networks
C. K. Pandiyarajan, M. Rubinstein, and J. Genzer
7/5/2016
Network dynamics in nanofilled polymers
G. P. Baeza, C. Dessi, S. Costanzo, D. Zhao, S. Gong, A. Alegria, R. H. Colby, M. Rubinstein, D. Vlassopoulos, and S. K. Kumar
4/25/2016
Submicrometer-Encapsulation of NaBH4 by Dopamine End-Functionalized Polystyrene: Gas Generation at Oil–Water Interfaces
M. Vatankhah-Varnoosfaderani, M. H. Everhart, A. P. Zhushma, M. Ina, and S. S. Sheiko
4/19/2016
Reversible shape‐shifting in polymeric materials
J. Zhou, and S. S. Sheiko
3/15/2016
Advancing Reversible Shape Memory by Tuning the Polymer Network Architecture
Q. Li, J. Zhou, M. Vatankhah-Varnoosfaderani, D. Nykypanchuk, O. Gang, and S. S. Sheiko
2/2/2016
Solvent-free, supersoft and superelastic bottlebrush melts and networks
W. F. M. Daniel, J. Burdyńska, M. Vatankhah-Varnoosfaderani, K. Matyjaszewski, J. Paturej, M. Rubinstein, A. V. Dobrynin, and S. S. Sheiko
11/30/2015
Universal behavior of hydrogels confined to narrow capillaries
Y. Li, O. S. Sarıyer, A. Ramachandran, S. Panyukov, M. Rubinstein, and E. Kumacheva
11/24/2015
Matrix-free Particle Brush System with Bimodal Molecular Weight Distribution Prepared by SI-ATRP
J. Yan, T. Kristufek, M. Schmitt, Z. Wang, G. Xie, A. Dang, C. M. Hui, J. Pietrasik, M. R. Bockstaller, and K. Matyjaszewski
11/9/2015
Weak Hydrogen Bonding Enables Hard, Strong, Tough, and Elastic Hydrogels
X. Hu, M. Vatankhah‐Varnoosfaderani, J. Zhou, Q. Li, and S. S. Sheiko
10/5/2015
Soft Poly(dimethylsiloxane) Elastomers from Architecture‐Driven Entanglement Free Design
L. Cai, T. E. Kodger, R. E. Guerra, A. F. Pegoraro, M. Rubinstein, and D. A. Weitz
8/10/2015
Isothermal programming of triple shape memory
J. Zhou, Q. Li, S. A. Turner, V. S. Ashby, and S. S. Sheiko
8/1/2015
Computer Simulations of Bottle Brushes: From Melts to Soft Networks
Z. Cao, J. Y. Carrillo, S. S. Sheiko, and A. V. Dobrynin
7/13/2015
Elastin-like Polypeptide Diblock Copolymers Self-Assemble into Weak Micelles
W. Hassouneh, E. B. Zhulina, A. Chilkoti, and M. Rubinstein
6/11/2015
Strong Selective Adsorption of Polymers
T. Ge, and M. Rubinstein
5/20/2015
Influence of the Solvent Quality on Ring Polymer Dimensions
S. Gooßen, A. R. Brás, W. Pyckhout-Hintzen, A. Wischnewski, D. Richter, M. Rubinstein, J. Roovers, P. J. Lutz, Y. Jeong, T. Chang, and D. Vlassopoulos
2/23/2015
Hopping Diffusion of Nanoparticles in Polymer Matrices
L. Cai, S. Panyukov, and M. Rubinstein
1/22/2015
Rouse mode analysis of chain relaxation in polymer nanocomposites
J. T. Kalathi, S. K. Kumar, M. Rubinstein, and G. S. Grest
1/1/2015

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