Elucidating Salt Effects on Chitosan Dynamics

7/21/2017 | Gregory Payne and Jana Shen

Using molecular dynamics simulations, we explored the solution salt effect on the conformational dynamics of chitosan chains. Our data revealed that the chitosan glycosidic bonds can rotate to an extended syn and the so-called anti-Ψ conformations.

Strain at Interfaces in Organic Devices

7/1/2017 | C. Risko & J. Anthony (U. Kentucky); O. Jurchescu (Wake Forest U.)

The impact of inhomogeneous strain induced in an organic semiconductor was evaluated by virtue of the mismatch in the coefficients of thermal expansion of the consecutive layers on the transistor properties.

Controlled 3D Assembly of Graphene Sheets

3/6/2017 | Andrey Dobrynin and Douglas Adamson

Graphene is a two-dimensional carbon sheet that stacks together to make graphite, much like the playing cards in a deck. Utilizing the attraction of graphene sheets to the high energy interface between two immiscible liquids such as oil and water, we are able to drive the self-rearrangement graphene sheets, as the graphite exfoliates and covers the high energy liquid-liquid interface.

Reconfiguring Hydrogels by Switching Crosslinks

2/20/2017 | Gregory Payne

In order for biological systems to grow, heal and adapt they must be able to dynamically reconfigure. Using biology as a model, we created a hydrogel with reversibly reconfigurable mechanical properties based on the switching between two physical crosslinking mechanisms. Specifically, we used the renewable aminopolysaccharide chitosan and switched this hydrogel between an elastic crystalline network and a viscoelastic electroastatically crosslinked network.

Crystallographic Distribution of Curvatures in Steel

1/15/2017

How is the motion of an interface between two solid crystals related to its shape? This is a question that was impossible to address in the past because we were not able to see within solids

Tuning Organic Solar Cell Domain Properties

1/1/2017 | Zhenan Bao, Michael Toney

Despite having achieved the long sought-after performance of 10% power conversion efficiency, high performance organic solar cells are still constrained to small devices fabricated by spin coating. Efforts to scale up via printing lag considerably behind, revealing an extreme sensitivity to different fabrication methods.

Extreme Quantum Confinement Heterostructures

12/1/2016 | D. Bayerl, S. Islam, C. M. Jones, V. Protasenko, D. Jena, and E. Kioupakis

In conventional semiconductor quantum heterostructures such as quantum wells based on GaAs or InAs that power today’s high-speed transistors in our cell phones, or the lasers in fiber-optic communication systems that carry our emails across the globe, it is necessary to precisely tune the energy of the electrons by quantum confinement

Enlisting Synbio for Molecular Communication

11/18/2016 | Gregory Payne and William Bentley

Divergent approaches to process information: •Electronics use electrons •Biology uses ions & molecules

Extending Reverse Engineering to Biology

6/1/2016 | Gregory Payne and William Bentley

In our research, we are developing novel experimental methods to characterize the redox-properties of our thin films. These characterization methods can also be extended to probe the properties of biological materials.

Observation of Structural Phase Changes Driven by Electrostatic Gating

10/13/21 | Evan J. Reed

We predicted that 2H-to-1T’ structural phase transformations in monolayer MoTe2 can be driven by electrostatic gating. Our predictions were confirmed in the lab, where our collaborators employed ionic liquids to gate the monolayer

Research Highlights