Storing Information with Magnetic Encoding

3/20/2018 | I. Cohen, P. McEuen (Cornell U.) and M. Brenner (Harvard U.)

Biological materials gain complexity from the programmable nature of their parts. To synthetically manufacture materials with comparable complexity, building blocks need to be created with low crosstalk when they only bind to their desired partners. Canonically, these building blocks are made using DNA strands or proteins to achieve specificity. Here Harvard and Cornell's researchers propose a new materials platform, Magnetic Handshake Materials, with programmable interactions using patterns of magnetic dipoles. This is a complete synthetic platform, enabled by magnetic printing technology, which is easier to both control and model in the laboratory.

Superconductivity in Twisted Trilayer Graphene

3/20/2018 | P. Kim, E. Kaxiras (Harvard) M. Luskin, K. Wang (U. Minnesota)

Layers of two-dimensional materials stacked with a small twist angle give rise to beating periodic patterns on a scale much larger than the original lattice, referred to as a ‘moiresuperlattice’. Superconductivity and correlated insulator states in magic angle alternatively twisted trilayer graphene (MA-tTG)1 (Fig., top) and ‘moire of moire’ twisted trilayer graphene (MM-tTG)2 (Fig., bottom) have now been experimentally demonstrated.

New Paradigm for the Design of Emergent Function

3/20/2018 | I. Cohen and P. McEuen (Cornell U.)

Systems composed of many interacting elements that collaboratively generate a function, such as meta-material robots, proteins, and neural networks are often not amenable to compartmentalized design: where individual modules each perform a distinct subfunction and are composed to create a complex function. A team at Cornell recently pursued an alternative design paradigm where the function of a machine arises simultaneously from interactions of all the machine components, and the operation of the machine is organized by a bifurcation of multiple equilibria - defined as the point where the machine transitions from having one possible configuration to a number of possible configurations.

Engineering Broad Range Temperature Active Enzymes

3/20/2018 | Sapna Sarupria (U. Minnesota)

Enzymes are eco-friendly and natural molecules with excellent properties. It is highly desirable to rationally engineer enzymes for target application in pharmaceutical, textile, and food industries. However, there are no clear design principles that enable this using rational site-directed mutagenesis approaches. In this work, molecular dynamics simulations were used to probe the activity–temperature relation used to explain the tradeoff between activity and stability in thermophilic and psychrophilic enzymes.

Reverse Engineering of Materials Properties

10/15/2017 | Gregory Payne and William Bentley

Traditional materials science approaches to characterize materials from nature or to develop new polymeric materials start by resolving chemical structure. Yet this approach fails for materials that have complex and ill-defined structures or that undergo dynamic changes as part of their function. This is the case for melanin a ubiquitous pigment in nature that is believed to offer protective antioxidant and radical scavenging properties.

Elucidating Salt Effects on Chitosan Dynamics

7/21/2017 | Gregory Payne and Jana Shen

Using molecular dynamics simulations, we explored the solution salt effect on the conformational dynamics of chitosan chains. Our data revealed that the chitosan glycosidic bonds can rotate to an extended syn and the so-called anti-Ψ conformations.

Strain at Interfaces in Organic Devices

7/1/2017 | C. Risko & J. Anthony (U. Kentucky); O. Jurchescu (Wake Forest U.)

The impact of inhomogeneous strain induced in an organic semiconductor was evaluated by virtue of the mismatch in the coefficients of thermal expansion of the consecutive layers on the transistor properties.

Controlled 3D Assembly of Graphene Sheets

3/6/2017 | Andrey Dobrynin and Douglas Adamson

Graphene is a two-dimensional carbon sheet that stacks together to make graphite, much like the playing cards in a deck. Utilizing the attraction of graphene sheets to the high energy interface between two immiscible liquids such as oil and water, we are able to drive the self-rearrangement graphene sheets, as the graphite exfoliates and covers the high energy liquid-liquid interface.

Reconfiguring Hydrogels by Switching Crosslinks

2/20/2017 | Gregory Payne

In order for biological systems to grow, heal and adapt they must be able to dynamically reconfigure. Using biology as a model, we created a hydrogel with reversibly reconfigurable mechanical properties based on the switching between two physical crosslinking mechanisms. Specifically, we used the renewable aminopolysaccharide chitosan and switched this hydrogel between an elastic crystalline network and a viscoelastic electroastatically crosslinked network.

Crystallographic Distribution of Curvatures in Steel

1/15/2017

How is the motion of an interface between two solid crystals related to its shape? This is a question that was impossible to address in the past because we were not able to see within solids

Research Highlights